Direct glucosone-based synthesis and HILIC-ESI-MS/MS characterization of N-terminal fructosylated valine and valylhistidine for validation of enzymatic HbA1c assays in the diagnosis of diabetes mellitus,
Ch. Gerke, M. Buchholz, H. Müller, R. Meusinger, M. Grimmler, E. Metzmann, Analytical and Bioanalytical Chemistry 2019, 411, 7967–7979

1,2-Oxazines as Building Blocks for Stereoselective Synthesis: Preparation of Oxygen-Substituted 1,2-Oxazines, either by Alcohol Addition or by Epoxidation, and Subsequent Hydrogenation Leading to 1,2-Amino Alcohols and Pyrrolidines,
R. Zimmer, M. Buchholz, M. Collas, J. Angermann, K. Homann, H.-U. Reissig, Eur. J. Org. Chem. 2010, 4111-4121.

Improved Synthesis of 3-Aminoestrone,
U. Schön, J. Messinger, M. Buchholz, U. Reinecker, H. Thole, M.K.S. Prabu, A. Konda, Tetrahedron Letters 2005, 46, 7111-7115.

Enantioselective Synthesis of the Pyrrolidine Core of Endothelin Antagonist ABT-627 (Atrasentan) via 1,2-Oxazines,
M. Buchholz, H.-U. Reissig, Eur. J. Org. Chem. 2003, 3524-3533.

Solid-Phase-Construction. High Efficiency Dendrimer Synthesis Using AB3 Isocyanate Type Monomers,
S. Lebreton, S. How, M. Buchholz, B. Yingyongnarongkul, M. Bradley, Tetrahedron 2003, 59, 3945-3953.

Synthesis of Enantioenriched 2-Substituted 4-Phenylbutylamines by Hydrogenolysis of Optically Pure 6-Alkoxy-5,6-dihydro-4H-1,2-oxazines,
M. Buchholz, F. Hiller, H.-U. Reissig, Eur. J. Org. Chem. 2002, 2838-2843.

Highly Stereoselective and Flexible Synthesis of 6-Alkoxy-5,6-dihydro-4H-1,2-Oxazines by Conjugate Addition of Organolithium Compounds to 6H-1,2-Oxazines Followed by Trapping with Electrophiles,
M. Buchholz, H.-U. Reissig, Synthesis 2002, 1412-1422.

Crystal structure of (4R*,5S*,6R*)-6-Ethoxy-4-[(1S*)-(1-hydroxy-1-phenyl)methyl]-3,5-diphenyl-5,6-dihydro-4H-1,2-oxazine,
H. Hartl, I. Brüdgam, H.-U. Reißig, M. Buchholz, Z. Kristallogr. NCS 2001, 216, 591-592.

Preparation of Cyclobutyl Group Carrying Cyclobutanones and Related Synthetic Building Blocks,
E.V. Dehmlow, J. Kinnius, M. Buchholz, D. Hannemann, J. Prakt. Chem. 2000, 342, 409-413.



Novel C11 Modified Retrosteroids as Progesterone Receptor Modulator Compounds,
J. Messinger, Ch. Böcker, H.-H. Thole, B. Husen, M. Hinaje, M. Buchholz, US2008249075, 2008.

Novel C18 Modified Retrosteroids as Progesterone Receptor Modulator Compounds,
J. Messinger, H.-H. Thole, B. Husen, Ch. Böcker, M. Hinaje, M. Buchholz, Ch. Mark, V.  Klinger-Dabral, WO2007039544, 2007.

Azaindol carboxamides,
P. Gmeiner, K. Schlotter, H. Hübner, D. Schmidt, M. Buchholz, WO2006050976, 2006.